Parallel Fabrication of Self‐Assembled Nanogaps for Molecular Electronic Devices
Journal article, 2018

Single molecule electronics might be a way to add additional function to nanoscale devices and continue miniaturization beyond current state of the art. Here, a combined top‐down and bottom‐up strategy is employed to assemble single molecules onto prefabricated electrodes. Protodevices, which are self‐assembled nanogaps composed by two gold nanoparticles linked by a single or a few molecules, are guided onto top‐down prefabricated nanosized nickel electrodes with sandwiched palladium layers. It is shown that an optimized geometry of multilayered metallic (top‐down) electrodes facilitates the assembly of (bottom‐up) nanostructures by surface charge interactions. Moreover, such assembly process results in an electrode–nanoparticle interface free from linking molecules that enable electrical measurements to probe electron transport properties of the nanoparticle–molecule–nanoparticle protodevices.

self-assembly

molecular electronics

nanofabrication

Author

Johnas Eklöf

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Kasper Moth-Poulsen Group

Tina Gschneidtner

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Polymer Technology

Behabitu Ergette Tebikachew

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Polymer Technology

Samuel Lara-Avila

Kasper Moth-Poulsen

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Kasper Moth-Poulsen Group

Small

1613-6810 (ISSN) 1613-6829 (eISSN)

Vol. 0 1803471

Single Molecule Nano Electronics (SIMONE)

European Commission (FP7), 2014-02-01 -- 2019-01-31.

Areas of Advance

Nanoscience and Nanotechnology

Materials Science

Subject Categories

Materials Chemistry

Nano Technology

DOI

10.1002/smll.201803471

More information

Created

11/7/2018