Selective deposition of metal oxide nanoflakes on graphene electrodes to obtain high-performance asymmetric micro-supercapacitors
Artikel i vetenskaplig tidskrift, 2021

To meet the charging market demands of portable microelectronics, there has been a growing interest in high performance and low-cost microscale energy storage devices with excellent flexibility and cycling durability. Herein, interdigitated all-solid-state flexible asymmetric micro-supercapacitors (A-MSCs) were fabricated by a facile pulse current deposition (PCD) approach. Mesoporous Fe2O3 and MnO2 nanoflakes were functionally coated by electrodeposition on inkjet-printed graphene patterns as negative and positive electrodes, respectively. Our PCD approach shows significantly improved adhesion of nanostructured metal oxide with crack-free and homogeneous features, as compared with other reported electrodeposition approaches. The as-fabricated Fe2O3/MnO2 A-MSCs deliver a high volumetric capacitance of 110.6 F cm(-3) at 5 mu A cm(-2) with a broad operation potential range of 1.6 V in neutral LiCl/PVA solid electrolyte. Furthermore, our A-MSC devices show a long cycle life with a high capacitance retention of 95.7% after 10 000 cycles at 100 mu A cm(-2). Considering its low cost and potential scalability to industrial levels, our PCD technique could be an efficient approach for the fabrication of high-performance MSC devices in the future.

Författare

Zhenyuan Xia

Chalmers, Industri- och materialvetenskap, Material och tillverkning

Viktoriia Mishukova

Kungliga Tekniska Högskolan (KTH)

Szymon Sollami Delekta

Kungliga Tekniska Högskolan (KTH)

Jinhua Sun

Chalmers, Industri- och materialvetenskap, Material och tillverkning

Jaime Sanchez Sanchez

Chalmers, Industri- och materialvetenskap, Material och tillverkning

Jiantong Li

Kungliga Tekniska Högskolan (KTH)

Vincenzo Palermo

Chalmers, Industri- och materialvetenskap, Material och tillverkning

Nanoscale

2040-3364 (ISSN)

Vol. 13 5 3285-3294

Ämneskategorier

Annan naturresursteknik

Materialkemi

Energisystem

DOI

10.1039/D0NR07076A

PubMed

33533790

Mer information

Senast uppdaterat

2021-05-18