Surface Interactions during Sintering of Chromium-alloyed PM Steels in Different Atmospheres
Paper in proceedings, 2010

Chromium is the one of the most attractive alloying elements in PM steels, nevertheless its high affinity to oxygen during sintering, especially during the heating stage, have to be considered. The type, morphology and distribution of the reaction products on the fracture surface of the pressed and sintered specimens of chromium-alloyed water atomized steel powders were studied by means of high resolution scanning electron microscopy (SEM including EDX). Specimens were sintered in three different atmospheres – nitrogen, nitrogen/10%hydrogen and vacuum. In all materials formation of particulate reaction products containing strong-oxide forming elements such as Cr, Si and Mn was detected. Positive effect of hydrogen on the oxides reduction during heating stage was observed. Preferred location of the inclusions inside the dimples of inter-particle ductile fracture indicates that they originate from fine particulates on the original powder surface that were enclosed during heating stage. Obtained results indicate that oxygen content can be significantly reduced by adjustment proper atmosphere purity/composition or high-temperature sintering.

sintering

sintering atmosphere

surface oxide

oxide reduction

chromium pre-alloyed powder

PM steel

spinel oxides

carbothermal reduction

Author

Dimitris Chasoglou

Chalmers, Materials and Manufacturing Technology, Surface and Microstructure Engineering

Eduard Hryha

Chalmers, Materials and Manufacturing Technology, Surface and Microstructure Engineering

Lars Nyborg

Chalmers, Materials and Manufacturing Technology, Surface and Microstructure Engineering

World Powder Metallurgy Congress and Exhibition, World PM 2010; Florence; Italy; 10 October 2010 through 14 October 2010

Vol. 2 3-12

Subject Categories

Materials Engineering

Manufacturing, Surface and Joining Technology

ISBN

978-189907219-4

More information

Created

10/7/2017