Recent Applications of Polymer Supported Organometallic Catalysts in Organic Synthesis
Journal article, 2010
Recent developments concerning the application of polymer supported organometallic reagents in solid phase synthesis are reviewed, with a special focus on methodology for carbon-carbon formation. Examples of reactions that are covered include the classical Suzuki, Sonogashira and Heck coupings, but also aryl amination, epoxide opening, rearrangements, metathesis and cyclopropanation. Applications in the field of asymmetric synthesis are also discussed.
allylic substitution
solid-phase synthesis
aryl chlorides
reactions
polymer supported
palladium complex
amphiphilic resin
transfer
hydrogenation
solid phase synthesis
cross-coupling
aryl amination
acrolein diethyl acetal
cross-coupling
mizoroki-heck reaction
supercritical carbon-dioxide
metathesis
n-heterocyclic carbenes
organometallic
bond-forming reactions
Author
Nina Kann
Chalmers, Chemical and Biological Engineering, Organic Chemistry
Molecules
1420-3049 (ISSN) 14203049 (eISSN)
Vol. 15 9 6306-6331Subject Categories
Chemical Sciences
DOI
10.3390/molecules15096306