Thermodynamic data provided through the FUNMIG project: Analyses and prospective
Journal article, 2012
In this paper some of the needs for good quality thermodynamic data in radioactive waste management are highlighted. A presentation of the thermodynamic data produced within the 6th EC framework programme integrated project FUNMIG (Fundamental processes of radionuclide migration) and how these have helped in filling relevant thermodynamic data gaps is given. The manuscript does not intend to be a complete review of thermodynamic data, but a short overview of the aqueous complexation of Am(III), lanthanides (III), U(VI), and Th(IV) by sulfates, silicates, carbonates and phosphates. The work presented is based on the latest developments published in the literature and specifically addressed within the IP FUNMIG.
sulfate
aqueous silicic-acid
solubility
complexation
perchlorate-media
induced fluorescence spectroscopy
limiting carbonate complexes
concentrated electrolyte-solutions
argillaceous formation
pore-water
chemistry
mass-spectrometry
Author
P. E. Reiller
The French Alternative Energies and Atomic Energy Commission (CEA)
T. Vercouter
The French Alternative Energies and Atomic Energy Commission (CEA)
L. Duro
Christian Ekberg
Chalmers, Chemical and Biological Engineering, Nuclear Chemistry
Applied Geochemistry
0883-2927 (ISSN) 18729134 (eISSN)
Vol. 27 2 414-426Subject Categories
Geophysics
DOI
10.1016/j.apgeochem.2011.09.011