Kinetic modeling of NH3-SCR over a supported Cu zeolite catalyst using axial species distribution measurements
Journal article, 2015
In this study, a kinetic model is developed for NH3-SCR over a honeycomb-monolith-supported Cu-zeolites using intra-catalyst axial species distribution measurements. An ammonia TPD experiment, together with micro calorimetry data were used for tuning the ammonia adsorption and desorption properties. The spatial distribution for NO oxidation, NH3 oxidation and NH3 "Standard" SCR were modeled between 200 and 400 degrees C. Four-step protocol measurements were employed in order to validate the transient functions of the model. The resulting kinetic model provides good spatiotemporal simulation of the SCR reaction and component reactions throughout the monolith catalyst system.
NH3 SCR
Cu zeolites
Spaci-MS
Spatial distribution measurements
Kinetic modeling
Author
Xavier Auvray
Chalmers, Chemistry and Chemical Engineering, Chemical Technology, Chemical Reaction Engineering
Competence Centre for Catalysis (KCK)
W. P. Partridge
Oak Ridge National Laboratory
J. S. Choi
Oak Ridge National Laboratory
J. A. Pihl
Oak Ridge National Laboratory
Filipa Coelho
Competence Centre for Catalysis (KCK)
Chalmers, Chemistry and Chemical Engineering, Chemical Technology, Chemical Reaction Engineering
A. Yezerets
Cummins Inc.
K. Kamasamudram
Cummins Inc.
N. W. Currier
Cummins Inc.
Louise Olsson
Competence Centre for Catalysis (KCK)
Chalmers, Chemistry and Chemical Engineering, Chemical Technology, Chemical Reaction Engineering
Applied Catalysis B: Environmental
0926-3373 (ISSN) 1873-3883 (eISSN)
Vol. 163 393-403Areas of Advance
Transport
Subject Categories
Chemical Engineering
DOI
10.1016/j.apcatb.2014.08.003