Applications of natural organic matter optical properties for assessing drinking water disinfection and distribution
Doctoral thesis, 2019

The task of providing safe drinking water requires proper monitoring of water quality and treatment performance from source to tap. Accordingly, the demand for online monitoring is increasing both at treatment plants a nd within distribution networks. Some of the available techniques use correlations between the optical properties of dissolved organic matter (DOM), mainly absorbance, and other water quality parameters. Fluorescence spectroscopy is significantly more sensitive than absorbance spectroscopy and gives comprehensive information about the composition and concentration of organic matter, so it has a strong potential for online monitoring applications. In this thesis, the application of fluorescence spectroscopy was investigated for two locations in the drinking water treatment system: the ultraviolet (UV) disinfection chambers and the distribution network. With respect to UV254disinfection, fluorescence spectroscopy was investigated as a proxy of potential unwanted by-products (assimilable organic carbon (AOC) and disinfection by products (DBPs), in addition to the administered UV dose. The UV254 irradiation increased assimilable organic carbon (AOC) concentration, with the estimated AOC production induced by UV254irradiation at a dose of 40 mJ cm-2being 0.4 % of the dissolved organic carbon. The concentration of adsorbable organic chlorine (AOCl), a subset of adsorbable organic halogens (AOX), generally increased following UV254 irradiation at the typical disinfection dose. Weak but statistically-significant correlations were found between the UV-induced fluorescence reduction and increases in both AOC and AOCl concentrations. Compared to absorbance, greater reductions were observed in fluorescence intensity following sequential UV irradiation and chlorination and these correlated more strongly with AOCl production. Following UV254disinfection, a linear relationship was observed between UV254dose and changes in long-wavelength fluorescence (> 400 nm) intensities at doses up to 200 mJ cm-2. However, the application of fluorescence as a proxy of the UV254dose is limited due to the relatively small and unpredictable direction of change of fluorescence intensity. In the distribution network, the sensitivity of fluorescence to detect contamination caused by entrainment was compared to the sensitivity of other common water quality parameters including several trace elements and microbial indicator species abundances. Of these, fluorescence was the most sensitive tracer for distinguishing contamination from natural variation, followed by absorbance. The relationship between fluorescence and microbial regrowth was also examined; however, no correlation was observed. The results of this thesis imply that although fluorescence might not always correlate with the chemical and microbial water parameters, its prompt response to treatment-induced modifications and fluctuations, together with high analytical precision and sensitivity of fluorescence measurements, make it a useful parameter for real-time monitoring of water quality changes in drinking water treatment plants and distribution systems.

assimilable organic carbon.

Optical properties

disinfection by-products

drinking water

UV disinfection

dissolved organic matter

distribution network

SB-H2, lecture hall, Sven Hultins Gata 6, Samhällsbyggnad
Opponent: Prof Jin Hur


Masoumeh Heibati

Chalmers, Architecture and Civil Engineering, Water Environment Technology

Drinking water is produced by treating raw water sourced from underground or lakes, and is distributed to consumers via the distribution network. One of the main components present in the water is the “natural organic matter”; a complex mixture of organic compounds derived from the degradation of plants and animals, which produce dyes that give water its characteristic yellowish colour. Natural organic matter reacts with disinfection chemicals to form unwanted products. Moreover, it acts as food source for microorganisms, potentially encouraging growth of harmful microorganisms, so called “pathogens”. Even in the distribution network, natural organic matter and pathogens may enter during pipe entrainment, resulting in deteriorating water quality. In this PhD dissertation, natural organic matter was studied in the final stages of Swedish drinking water treatment systems. Organic matter was characterised based on “water colour”, measured by spectroscopic techniques. For instance, in distribution systems, “water colour” could be used to assess microbial risk and deviations in water colour from normal levels might be a warning sign for contamination. Not only can “water colour” be measured quickly and inexpensively, as shown in this dissertation it is also sensitive enough to track small changes in water quality, therefore there is potential for measuring it online in order to provide a preliminary assessment of water quality.

Subject Categories

Water Engineering

Environmental Sciences



Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie: 4634



SB-H2, lecture hall, Sven Hultins Gata 6, Samhällsbyggnad

Opponent: Prof Jin Hur

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