Water/Ethanol Soluble p-Type Conjugated Polymers for the Use in Organic Photovoltaics
Journal article, 2020

We have developed two series of p-type conjugated polymers based on poly[2,3-bis-(3-octyloxyphenyl)quinoxaline-5,8-diyl-alt-thiophene-2,5-diyl] (TQ1) polymeric backbone utilizing polar pendant groups, i.e., tertiary amine and pyridine, to achieve switchable solubility in water and ethanol. By balancing the ratio between polar and non-polar side-groups, we could combine green-solvent processability with the manufacturing of functional photovoltaic devices. Due to the unavailability of water/alcohol soluble acceptors, the photovoltaic performance of these new polymers was evaluated using organic solvent by incorporating PC61BM. For water/alcohol soluble partial amine-based polymers, we achieve a maximum power conversion efficiency (PCE) of ∼0.8% whereas alcohol soluble partial pyridine-based polymers show enhanced PCE of ∼1.3% with inverted device structure. We propose that the enhancement in PCE is a result of the reduction in amino-group content and the lower basicity of pyridine, both of which decrease the interaction between functionalized polymers with the anode interface material and reduce the miscibility of the donor and acceptor. Further improvement of the photovoltaic performance, in particular the open-circuit voltage (Voc), was achieved by using an anode buffer layer to mitigate the unfavorable interaction of the amino/pyridine groups with the MoO3 electrode. Our work demonstrated the possibility of substituent modification for conjugated polymers using tertiary amine and pyridine groups to achieve water/alcohol soluble and functional donor materials.

side-chain modification

water/ethanol soluble

conjugated polymers

organic photovoltaics

switchable solubility

Author

Xun Pan

Flinders University

A. Sharma

King Abdullah University of Science and Technology (KAUST)

Renee Kroon

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Christian Müller Group

Desta Antenehe Gedefaw

University of the South Pacific

S. Elmas

Flinders University

Yanting Yin

Flinders University

G. Andersson

Flinders University

D. A. Lewis

Flinders University

Mats Andersson

Flinders University

Frontiers in Materials

22968016 (eISSN)

Vol. 7 281

Subject Categories

Polymer Chemistry

Polymer Technologies

Materials Chemistry

DOI

10.3389/fmats.2020.00281

More information

Latest update

10/14/2020