Global Kinetic Model of a Three-Way-Catalyst-Coated Gasoline Particulate Filter: Catalytic Effects of Soot Accumulation
Journal article, 2021

In the present study, a global kinetic model of three-way-catalyst-coated gasoline particulate filters was developed to understand the relevant kinetic mechanisms taking place both in clean and real soot-loaded filters. The model involves reaction rate expressions for CO, C2H4, and C7H8 conversion over a model Pd/CeZr/Al2O3 catalyst, hydrothermally treated at 650 °C. Particularly, a new rate expression was proposed for ethylene based on the distinctive experimental trends observed for this hydrocarbon. The model predicted satisfactorily the conversion of all three reductants under different experimental conditions. The soot inhibition effect was also modeled by the reduction of the number of active sites. Interestingly, ethylene was less affected compared to other reductants by the presence of soot due to the formation of less stable and more reactive species on the catalyst surface.

Soot

Ethylene

Cerium compounds

Gasoline

Kinetic theory

Catalysts

Dust

Kinetic parameters

Zirconium compounds

Palladium compounds

Author

Jesus De Abreu Goes

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Volvo

Louise Olsson

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Timothy C. Watling

Johnson Matthey

Industrial & Engineering Chemistry Research

0888-5885 (ISSN) 1520-5045 (eISSN)

Vol. 60 47 16899-16910

Kemisk åldring och regenerering av NOxfällor för mager drift

Swedish Foundation for Strategic Research (SSF) (ID15-0030), 2016-01-01 -- 2020-12-31.

Subject Categories

Pharmaceutical Sciences

Other Chemical Engineering

Biophysics

DOI

10.1021/acs.iecr.1c02742

More information

Latest update

4/5/2022 5