Characterization methods and modelling for Li-ion batteries: entropy, impedance, pressure, diffusivity & temperature swings induced aging
Doctoral thesis, 2022
During the study, a series of characterization methods were also developed, including a physics-based circuit model, a convenient method to measure the entropic coefficient, an on-line impedance measurement technique, an effective reference performance test procedure, and methods to measure the cell
pressure and thickness change during cycling. A selection of results are that the physics-based circuit model could predict key quantities, such as overpotential, concentrations etc., with less than 0.05% deviation compared with a state-of-art model. Furthermore, the on-line impedance measurement technique managed to extract the battery pack impedance between 0.01 Hz and 5 Hz based on CAN signals. In addition, the cell pressure and thickness change during cycling of a commercial cell were found to be up to 60 kPa and 150 μm.
characterization methods
swelling
temperature swing
model
impedance
lifetime
Li-ion batteries
thermal
pressure
entropy
aging
Author
Zeyang Geng
Chalmers, Electrical Engineering, Electric Power Engineering
In situ key aging parameter determination of a vehicle battery using only CAN signals in commercial vehicles
Applied Energy,;Vol. 314(2022)
Journal article
Validity of solid-state Li<sup>+</sup> diffusion coefficient estimation by electrochemical approaches for lithium-ion batteries
Electrochimica Acta,;Vol. 404(2022)
Journal article
Intermittent current interruption method for commercial lithium ion batteries aging characterization
IEEE Transactions on Transportation Electrification,;Vol. 8(2022)p. 2985-2995
Journal article
Bridging physics-based and equivalent circuit models for lithium-ion batteries
Electrochimica Acta,;Vol. 372(2021)
Journal article
A Time- and Cost-Effective Method for Entropic Coefficient Determination of a Large Commercial Battery Cell
IEEE Transactions on Transportation Electrification,;Vol. 6(2020)p. 257-266
Journal article
Lithium-ion batteries are commonly used for energy storage systems, and temperature is one key impact factor on the cell performance and lifetime. Up to now, the focus has been on the ambient temperature of the test condition, and there is little discussion about how the temperature swing during cycling affects the battery lifetime. In this study, lithium-ion cells are cycled with the same current but different temperature swings for more than two years. The results show that the cells cycled with a high temperature swing aged faster. Moreover, pure thermal cycling does not introduce significant aging to the cell. This thesis deals with the subject of how lithium batteries behave. The electrical behaviour and the ageing behaviour are in focus, but also the thermal and mechanical expansion behaviour are studied.
The work contains interesting and novel theory building. In addition, the experimental verification work has been very strong, involving a large number of advanced experiments.
Areas of Advance
Transport
Energy
Subject Categories
Electrical Engineering, Electronic Engineering, Information Engineering
ISBN
978-91-7905-655-1
Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie: 5121
Publisher
Chalmers
HC4, Hörsalsvägen 14, Göteborg
Opponent: Professor Gregory Offer, Imperial College London, UK