Effects of Flexible Conjugation-Break Spacers of Non-Conjugated Polymer Acceptors on Photovoltaic and Mechanical Properties of All-Polymer Solar Cells
Journal article, 2022
Highlights: A series of non-conjugated acceptor polymers with flexible conjugation-break spacers (FCBSs) of different lengths were synthesized.The effect of FCBSs length on solubility of the acceptor polymers, and their photovoltaic and mechanical properties in all-polymer solar cells were explored.This work provides useful guidelines for the design of semiconducting polymers by introducing FCBS with proper length, which can giantly improved properties that are not possible to be achieved by the state-of-the-art fully conjugated polymers. Abstract: All-polymer solar cells (all-PSCs) possess attractive merits including superior thermal stability and mechanical flexibility for large-area roll-to-roll processing. Introducing flexible conjugation-break spacers (FCBSs) into backbones of polymer donor (PD) or polymer acceptor (PA) has been demonstrated as an efficient approach to enhance both the photovoltaic (PV) and mechanical properties of the all-PSCs. However, length dependency of FCBS on certain all-PSC related properties has not been systematically explored. In this regard, we report a series of new non-conjugated PAs by incorporating FCBS with various lengths (2, 4, and 8 carbon atoms in thioalkyl segments). Unlike common studies on so-called side-chain engineering, where longer side chains would lead to better solubility of those resulting polymers, in this work, we observe that the solubilities and the resulting photovoltaic/mechanical properties are optimized by a proper FCBS length (i.e., C2) in PA named PYTS-C2. Its all-PSC achieves a high efficiency of 11.37%, and excellent mechanical robustness with a crack onset strain of 12.39%, significantly superior to those of the other PAs. These results firstly demonstrate the effects of FCBS lengths on the PV performance and mechanical properties of the all-PSCs, providing an effective strategy to fine-tune the structures of PAs for highly efficient and mechanically robust PSCs.[Figure not available: see fulltext.]
Mechanical robustness
Flexible conjugation-break spacers
All-polymer solar cells
Polymer acceptors
Stretchability
Author
Qiaonan Chen
Jinan University
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Yung Hee Han
Korea Advanced Institute of Science and Technology (KAIST)
Leandro Rezende Franco
Karlstad University
Cleber F.N. Marchiori
Karlstad University
Zewdneh Genene Wolkeba
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
C. Moyses Araujo
Karlstad University
Uppsala University
Jin Woo Lee
Korea Advanced Institute of Science and Technology (KAIST)
Tan Ngoc Lan Phan
Korea Advanced Institute of Science and Technology (KAIST)
Jingnan Wu
Aalborg University
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Donghong Yu
Aalborg University
Sino-Danish Center for Education and Research Denmark
Dong Jun Kim
Korea Advanced Institute of Science and Technology (KAIST)
Taek Soo Kim
Korea Advanced Institute of Science and Technology (KAIST)
Lintao Hou
Jinan University
Bumjoon J. Kim
Korea Advanced Institute of Science and Technology (KAIST)
Ergang Wang
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Zhengzhou University
Nano-Micro Letters
23116706 (ISSN) 21505551 (eISSN)
Vol. 14 1 164Next Generation Organic Solar Cells (OPV 2.0)
Swedish Research Council (VR) (2016-06146), 2017-01-01 -- 2022-12-31.
Swedish Research Council (VR) (2016-06146), 2017-01-01 -- 2022-12-31.
Swedish Research Council (VR) (2016-06146), 2017-01-01 -- 2022-12-31.
Understanding the fundamentals of light emitting electrochemical cells
Swedish Research Council (VR) (2019-02345), 2020-01-01 -- 2025-12-31.
Subject Categories (SSIF 2011)
Polymer Chemistry
Polymer Technologies
Textile, Rubber and Polymeric Materials
DOI
10.1007/s40820-022-00884-8
PubMed
35962874