Ionize Hard: Interstellar PO+ Detection
Journal article, 2022
We report the first detection of the phosphorus monoxide ion (PO+) in the interstellar medium. Our unbiased and very sensitive spectral survey toward the G+0.693–0.027 molecular cloud covers four different rotational transitions of this molecule, two of which (J = 1–0 and J = 2–1) appear free of contamination from other species. The fit performed, assuming local thermodynamic equilibrium conditions, yields a column density of N=(6.0 ± 0.7) × 1011 cm−2. The resulting molecular abundance with respect to molecular hydrogen is 4.5 × 10–12. The column density of PO+ normalized by the cosmic abundance of P is larger than those of NO+ and SO+, normalized by N and S, by factors of 3.6 and 2.3, respectively. The N(PO+)/N(PO) ratio is 0.12 ± 0.03, more than one order of magnitude higher than that of N(SO+)/N(SO) and N(NO+)/N(NO). These results indicate that P is more efficiently ionized than N and S in the ISM. We have performed new chemical models that confirm that the PO+ abundance is strongly enhanced in shocked regions with high values of cosmic-ray ionization rates (10–15 − 10–14 s−1), as occurring in the G+0.693–0.027 molecular cloud. The shocks sputter the interstellar icy grain mantles, releasing into the gas phase most of their P content, mainly in the form of PH3, which is converted into atomic P, and then ionized efficiently by cosmic rays, forming P+. Further reactions with O2 and OH produces PO+. The cosmic-ray ionization of PO might also contribute significantly, which would explain the high N(PO+)/N(PO) ratio observed. The relatively high gas-phase abundance of PO+ with respect to other P-bearing species stresses the relevance of this species in the interstellar chemistry of P.
phosphorus
interstellar: clouds
astrochemistry
interstellar: ions
interstellar: abundances
Author
Víctor M. Rivilla
Centro de Astrobiologia (CAB)
Juan García De La Concepción
Centro de Astrobiologia (CAB)
I. Jimenez-Serra
Centro de Astrobiologia (CAB)
J. Martin-Pintado
Centro de Astrobiologia (CAB)
L. Colzi
Centro de Astrobiologia (CAB)
B. Tercero
Spanish National Observatory (OAN)
Andrés Megías
Centro de Astrobiologia (CAB)
Álvaro López-Gallifa
Centro de Astrobiologia (CAB)
Antonio Martínez-Henares
Centro de Astrobiologia (CAB)
Sara Massalkhi
Centro de Astrobiologia (CAB)
S. Martin
European Southern Observatory Santiago
Atacama Large Millimeter-submillimeter Array (ALMA)
Shaoshan Zeng
RIKEN
P. de Vicente
Spanish National Observatory (OAN)
Fernando Rico-Villas
Centro de Astrobiologia (CAB)
M. A. Requena-Torres
University of Maryland
Towson University
Giuliana Cosentino
Chalmers, Space, Earth and Environment, Astronomy and Plasmaphysics
Frontiers in Astronomy and Space Sciences
2296987X (eISSN)
Vol. 9 829288Subject Categories
Physical Chemistry
Atom and Molecular Physics and Optics
Other Chemistry Topics
DOI
10.3389/fspas.2022.829288