An Alternative Method of Measuring Area Specific Resistance of Chromia Scales Using Electrochemical Impedance Spectroscopy
Journal article, 2023

A novel method that employs electrochemical impedance spectroscopy (EIS) is developed to characterize the oxide scale resistance and thickness of Crofer 22 APU after exposure at 800 °C in humidified air. Crofer 22 APU, is one of the most commonly used materials for solid oxide fuel cell (SOFC) interconnects, an application for which oxide scale resistance is of paramount importance. The kinetics of oxide growth were studied for up to 6,000 h using three different techniques: electron microscopy of cross-sections, gravimetry, and EIS capacitance measurements of the oxide scale. EIS was used to evaluate the scale thickness starting from the material capacitance, and the material resistance at high temperature was estimated using extrapolation of the impedance values at room temperature. The result obtained with this novel EIS method are comparable to those obtained using conventional techniques, and in addition, the new method is cheaper, faster, and more reliable. Moreover, it enables repetitive exposures of the same sample without altering the specimen properties.

Author

Alberto Visibile

Chalmers, Chemistry and Chemical Engineering, Energy and Material

Luca Gagliani

Chalmers, Chemistry and Chemical Engineering, Energy and Material

Elisabet Ahlberg

University of Gothenburg

Jan-Erik Svensson

Chalmers, Chemistry and Chemical Engineering, Energy and Material

Jan Froitzheim

Chalmers, Chemistry and Chemical Engineering, Energy and Material

Journal of the Electrochemical Society

0013-4651 (ISSN) 1945-7111 (eISSN)

Vol. 170 3 031505

Subject Categories

Ceramics

Materials Chemistry

Other Materials Engineering

DOI

10.1149/1945-7111/acc13e

More information

Latest update

4/13/2023