Mercury Removal from Concentrated Sulfuric Acid by Electrochemical Alloy Formation on Platinum
Journal article, 2023

Mercury is a highly toxic heavy metal, and improved removal processes are required in a range of industrial applications to limit the environmental impacts. At present, no viable removal methods exist commercially for mercury removal of aqueous solutions at high acidic conditions, such as concentrated sulfuric acid. Herein, we show that electrochemical mercury removal based on electrochemical alloy formation on platinum, forming PtHg4, can be used to remove mercury from concentrated sulfuric acid. Thin platinum film electrodes and porous electrodes with supported platinum are used to remove more than 90% of mercury from concentrated acid from a zinc smelter with an initial mercury concentration of 0.3-0.9 mg/kg, achieving high-quality acid (<0.08 mg/kg) within 80 h. The removal process is carried out in 50 mL laboratory-scale experiments and scaled up to a 20 L pilot reactor with retained removal efficiency, highlighting excellent scalability of the method. In addition, the removal efficiency and stability of different electrode substrate materials are studied to ensure high-quality acid and a long lifetime of the electrodes in harsh chemical conditions, offering a potential method for future large-scale mercury decontamination of sulfuric acid.

platinum

electrochemistry

mercury removal

alloy formation

sulfuric acid

Author

Vera Roth

Chalmers, Physics, Chemical Physics

Julia Järlebark

Stena Center

Alexander Ahrnens

Stena Center

Jens Nyberg

Boliden Group

Justin Salminen

Boliden Group

Teodora Retegan Vollmer

Chalmers, Chemistry and Chemical Engineering, Energy and Material

Björn Wickman

Chalmers, Physics, Chemical Physics

ACS ES and T Engineering

26900645 (eISSN)

Vol. 3 6 823-830

Subject Categories

Inorganic Chemistry

Chemical Process Engineering

Other Chemical Engineering

Other Chemistry Topics

DOI

10.1021/acsestengg.2c00417

More information

Latest update

7/24/2023