Chiral Polaritonics: Analytical Solutions, Intuition, and Use
Journal article, 2023

Preferential selection of a given enantiomer over its chiral counterpart has become increasingly relevant in the advent of the next era of medical drug design. In parallel, cavity quantum electrodynamics has grown into a solid framework to control energy transfer and chemical reactivity, the latter requiring strong coupling. In this work, we derive an analytical solution to a system of many chiral emitters interacting with a chiral cavity similar to the widely used Tavis-Cummings and Hopfield models of quantum optics. We are able to estimate the discriminating strength of chiral polaritonics, discuss possible future development directions and exciting applications such as elucidating homochirality, and deliver much needed intuition to foster the newly flourishing field of chiral polaritonics.

Author

Christian Schäfer

Chalmers, Physics, Condensed Matter and Materials Theory

Denis G. Baranov

Moscow Institute of Physics and Technology

Journal of Physical Chemistry Letters

1948-7185 (eISSN)

Vol. 14 15 3777-3784

Kvantplasmonik – en teknologi för foton-fotonväxelverkan på kvantnivå vid rumstemperatur

Swedish Research Council (VR) (2016-06059), 2017-01-01 -- 2022-12-31.

Subject Categories

Analytical Chemistry

Software Engineering

Computer Science

Computer Systems

DOI

10.1021/acs.jpclett.3c00286

PubMed

37052302

More information

Latest update

5/9/2023 1