Binder Jetting – Influence of the Processing Atmosphere on Process Robustness and Part Quality of 17-4 PH Stainless Steel
Doctoral thesis, 2025

Debinding

Powder Reuse

Additive Manufacturing

Oxidation

Processing Atmosphere

Stainless Steel

Sintering

Carbothermal Reduction

Curing

Binder Jetting

Virtual Development Laboratory (VDL), Chalmers Tvärgata 4C, Chalmers University of Technology
Opponent: Professor Thomas Weißgärber, TU Dresden, Germany

Author

Kai Zissel

Chalmers, Industrial and Materials Science, Materials and manufacture

Kai Zissel, Sophie Dubiez-Le Goff, Eduard Hryha: Binder Jetting – Impact of powder reuse and curing on powder characteristics, green parts and sintering densification of 17-4 PH stainless steel

Sofia Kazi, Kai Zissel, Eduard Hryha: The impact of oxidation during curing of binder jetted 17-4 PH stainless steel on powder properties and powder surface chemistry

Kai Zissel, Gowtham Soundarapandiyan, Sophie Dubiez-Le Goff, Eduard Hryha: Binder Jetting – Influence of shell printing on sintering densification and microstructure of 17-4 PH stainless steel

Binder Jetting - Influence of Processing Atmospheres on Sintering Anisotropy of 17-4 PH Stainless Steel

Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy,;Vol. 72(2025)p. S1065-S1072

Journal article

Kai Zissel, Anok Babu Nagaram, Sophie Dubiez-Le Goff, Eduard Hryha: Impact of debinding atmosphere composition on binder removal and powder oxidation of binder jetted 17-4 PH stainless steel

Optimizing Binder Jetting through Controlled Processing Atmospheres

Binder Jetting (BJT) is a promising 3D printing technology for creating complex metal parts with high productivity and low costs. BJT works like an inkjet printer but uses thin layers of metal powder instead of paper. Instead of ink, a liquid glue (binder) is jetted onto the powder layer. Layers are printed on top of each other, gluing the particles together.

Once printed, the glued part is “hardened” (curing) in an oven, allowing the part to be freed from the surrounding unglued powder. Afterward, the part is placed into a furnace to burn out the binder (debinding) at elevated temperatures and bake the metal powders together (sintering) near the melting temperature.

This research examined how the atmosphere during curing, debinding and sintering affects the BJT process and final part quality. Curing in air causes powder oxidation, which makes reusing unglued powder problematic. Switching to an inert atmosphere solves this as it prevents oxidation.

Debinding and sintering in inert atmospheres leave harmful binder residues in the part, reducing the part quality. Efficient debinding requires reactive molecules like oxygen or hydrogen. While debinding and sintering in hydrogen is effective, the explosiveness makes it unpopular. A safer alternative is debinding in an oxygen-containing atmosphere followed by sintering under an inert gas. Reducing the oxygen content during debinding compared to air balances binder removal and powder oxidation, improving the final part quality.

Subject Categories (SSIF 2025)

Materials Engineering

Areas of Advance

Materials Science

ISBN

978-91-8103-207-9

Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie: 5665

Publisher

Chalmers

Virtual Development Laboratory (VDL), Chalmers Tvärgata 4C, Chalmers University of Technology

Online

Opponent: Professor Thomas Weißgärber, TU Dresden, Germany

More information

Latest update

5/2/2025 1