Binder Jetting – Influence of the Processing Atmosphere on Process Robustness and Part Quality of 17-4 PH Stainless Steel
Doctoral thesis, 2025
Debinding
Powder Reuse
Additive Manufacturing
Oxidation
Processing Atmosphere
Stainless Steel
Sintering
Carbothermal Reduction
Curing
Binder Jetting
Author
Kai Zissel
Chalmers, Industrial and Materials Science, Materials and manufacture
Kai Zissel, Sophie Dubiez-Le Goff, Eduard Hryha: Binder Jetting – Impact of powder reuse and curing on powder characteristics, green parts and sintering densification of 17-4 PH stainless steel
Sofia Kazi, Kai Zissel, Eduard Hryha: The impact of oxidation during curing of binder jetted 17-4 PH stainless steel on powder properties and powder surface chemistry
Kai Zissel, Gowtham Soundarapandiyan, Sophie Dubiez-Le Goff, Eduard Hryha: Binder Jetting – Influence of shell printing on sintering densification and microstructure of 17-4 PH stainless steel
Binder Jetting - Influence of Processing Atmospheres on Sintering Anisotropy of 17-4 PH Stainless Steel
Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy,;Vol. 72(2025)p. S1065-S1072
Journal article
Impact of oxygen content on debinding of binder jetted 17-4 PH stainless steel: Part I - Debinding
Powder Metallurgy,;Vol. 68(2024)p. 3-15
Journal article
Impact of oxygen content on debinding of binder jetted 17-4 PH stainless steel: Part II - Sintering
Powder Metallurgy,;Vol. 68(2024)p. 16-28
Journal article
Kai Zissel, Anok Babu Nagaram, Sophie Dubiez-Le Goff, Eduard Hryha: Impact of debinding atmosphere composition on binder removal and powder oxidation of binder jetted 17-4 PH stainless steel
Binder Jetting (BJT) is a promising 3D printing technology for creating complex metal parts with high productivity and low costs. BJT works like an inkjet printer but uses thin layers of metal powder instead of paper. Instead of ink, a liquid glue (binder) is jetted onto the powder layer. Layers are printed on top of each other, gluing the particles together.
Once printed, the glued part is “hardened” (curing) in an oven, allowing the part to be freed from the surrounding unglued powder. Afterward, the part is placed into a furnace to burn out the binder (debinding) at elevated temperatures and bake the metal powders together (sintering) near the melting temperature.
This research examined how the atmosphere during curing, debinding and sintering affects the BJT process and final part quality. Curing in air causes powder oxidation, which makes reusing unglued powder problematic. Switching to an inert atmosphere solves this as it prevents oxidation.
Debinding and sintering in inert atmospheres leave harmful binder residues in the part, reducing the part quality. Efficient debinding requires reactive molecules like oxygen or hydrogen. While debinding and sintering in hydrogen is effective, the explosiveness makes it unpopular. A safer alternative is debinding in an oxygen-containing atmosphere followed by sintering under an inert gas. Reducing the oxygen content during debinding compared to air balances binder removal and powder oxidation, improving the final part quality.
Subject Categories (SSIF 2025)
Materials Engineering
Areas of Advance
Materials Science
ISBN
978-91-8103-207-9
Doktorsavhandlingar vid Chalmers tekniska högskola. Ny serie: 5665
Publisher
Chalmers
Virtual Development Laboratory (VDL), Chalmers Tvärgata 4C, Chalmers University of Technology
Opponent: Professor Thomas Weißgärber, TU Dresden, Germany