Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net
Journal article, 2009
The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-μ1,1-azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.
magnetism
Coordination
X-ray structure analysis
Author
Al-Shimaà A A Massoud
Chalmers, Chemical and Biological Engineering, Physical Chemistry
Morsy A.M. Abu-Youssef
Alexandria University
Jana Poltierova Vejpravova
Charles University
Vratislav Langer
Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry
Lars Öhrström
Chalmers, Chemical and Biological Engineering, Physical Chemistry
CrystEngComm
14668033 (eISSN)
Vol. 11 2 223-225Subject Categories
Inorganic Chemistry
Condensed Matter Physics
DOI
10.1039/b815264k