Nighttime chlorine monoxide observations by the Odin satellite and implications for the ClO/Cl2O2 equilibrium
Journal article, 2005
We use measurements of chlorine monoxide (ClO) by the SMR instrument onboard the Odin satellite to study the nighttime thermal equilibrium between ClO and its dimer Cl2O2. Observations performed in the polar vortex during the 2002-2003 Arctic winter showed enhanced amounts of nighttime ClO over a wide range of stratospheric temperatures (185 < T < 225 K). Odin/SMR measurements are here compared to three-dimensional model calculations using various published estimations of the K-eq equilibrium constant between ClO and Cl2O2. Our results show that the value of K-eq currently recommended by JPL (Sander et al., 2003) leads to a large underestimation of the observed nighttime ClO amounts, and that a realistic estimation of K-eq must lie between the values determined by Cox and Hayman (1988) and Von Hobe et al. (2005).
Author
G. Berthet
Institut Pierre Simon Laplace Ecole polytechnique
University of Cambridge
P. Ricaud
Laboratoire dAerologie UMR 5560
F. Lefévre
Institut Pierre Simon Laplace Ecole polytechnique
E. Le Flochmoën
Laboratoire dAerologie UMR 5560
Joachim Urban
Chalmers, Department of Radio and Space Science, Global Environmental Measurements
B. Barret
Laboratoire dAerologie UMR 5560
N. Lautié
Chalmers
E. Dupuy
Observatoire Aquitain des Sciences de l'Univers, OASU
J. De La Noë
Observatoire Aquitain des Sciences de l'Univers, OASU
Donal Murtagh
Chalmers, Department of Radio and Space Science, Global Environmental Measurements
Geophysical Research Letters
0094-8276 (ISSN)
Vol. 32 11 1-5Subject Categories
Meteorology and Atmospheric Sciences
DOI
10.1029/2005GL022649