Effect of nanofillers on the flame retardant properties of a polyethylene-calcium carbonate-silicone elastomer system
Journal article, 2011

This study shows the effects of three different nanofillers on the viscosity properties and fire behavior of a halogen-free flame retardant system. The original system, based on ethylene-acrylate copolymer, calcium carbonate, and a silicone elastomer, shows good flame retardant properties. One of the nanofillers, montmorillonite (MMT), significantly increases the viscosity above 250 degrees C, resulting in reduced dripping and decreased heat release rate. The ash residue, however, is very brittle, indicating poor interactions between the MMT and other components of the system. The second nanofiller, sepiolite, shows no improvement on the flame retardant properties of the system. Reduced dripping is observed when a small amount of the third nanofiller, polyhedral oligomeric silsesquioxane, POSS, is incorporated into the system. In this case, high silica content on the surface indicates char formation originating from the POSS. However, an increased heat release is observed when POSS is used in the system.

nanofiller

flame retardant

behavior

viscosity

chalk

acrylate

ethylene-acrylate copolymer

polymer nanocomposites

polypropylene

Author

Linus Karlsson

Chalmers, Chemical and Biological Engineering, Polymer Technology

A. Lundgren

Stiftelsen Chalmers Industriteknik

J. Jungqvist

Borealis GmbH

Thomas Hjertberg

Borealis GmbH

Fire and Materials

0308-0501 (ISSN) 1099-1018 (eISSN)

Vol. 35 7 443-452

Subject Categories

Chemical Engineering

DOI

10.1002/fam.1064

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Latest update

10/9/2023