Structure and magnetic properties of a trinuclear nickel(II) complex with benzenetricarboxylate bridge
Journal article, 2008

Novel trinuclear Ni(II) complex [Ni3(pmdien)3(btc)(H2O)3](ClO4)3·4H2O, 1 where pmdien = N,N,N′,N′,N″-pentamethyldiethylenetriamine, H3btc = 1,3,5-benzenetricarboxylic (trimesic) acid, has been prepared and structurally characterized. Three nickel atoms are bridged by btc trianion and their coordination sphere is completed by three N atoms of pmdien and O atom of the water molecule. The three nickel(II) magnetic centers are equivalent and their coordination spheres are completed to deformed octahedrons. Magnetic susceptibility was measured over the temperature range 1.8–300 K and zJ′ = −0.19 cm−1, D = 3.79 cm−1, g = 2.18 parameters were calculated.

crystal structure

trimesic acid

Nickel complex

trinuclear complexes

magnetism

benzenetricarboxylate

Author

Jerzy Mrozinski

University of Wroclaw

Alina Bienko

University of Wroclaw

Pavel Kopel

AVX Czech Republic

Vratislav Langer

Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry

Inorganica Chimica Acta

0020-1693 (ISSN)

Vol. 361 12-13 3723-3729

Subject Categories

Organic Chemistry

Condensed Matter Physics

DOI

10.1016/j.ica.2008.04.005

More information

Created

10/7/2017