Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net
Journal article, 2009
The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-μ1,1-azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.
magnetism
Coordination
X-ray structure analysis
Author
Al-Shimaà A A Massoud
Chalmers, Chemical and Biological Engineering, Physical Chemistry
Morsy A.M. Abu-Youssef
Alexandria University
Jana Poltierova Vejpravova
Charles University
Vratislav Langer
Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry
Lars Öhrström
Chalmers, Chemical and Biological Engineering, Physical Chemistry
CrystEngComm
1466-8033 (ISSN)
Vol. 11 2 223-225Subject Categories
Inorganic Chemistry
Condensed Matter Physics
DOI
10.1039/b815264k