Methyl groups control coordination number, stoichiometry, network and magnetism in a Cu(II)-azide-pyrazine (6,3) 2D net
Journal article, 2009

The methyl groups of [Cu2(2,5-dimethylpyrazine)(N3)4]n, 1, force penta-coordination on the Cu(II) ions, which, together with the di-μ1,1-azido zigzag chains, result in a (6,3) 2D net with dominant ferromagnetic interactions.

magnetism

Coordination

X-ray structure analysis

Author

Al-Shimaà A A Massoud

Chalmers, Chemical and Biological Engineering, Physical Chemistry

Morsy A.M. Abu-Youssef

Alexandria University

Jana Poltierova Vejpravova

Charles university

Vratislav Langer

Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry

Lars Öhrström

Chalmers, Chemical and Biological Engineering, Physical Chemistry

CrystEngComm

1466-8033 (ISSN)

Vol. 11 2 223-225

Subject Categories

Inorganic Chemistry

Condensed Matter Physics

DOI

10.1039/b815264k

More information

Latest update

6/14/2018