The correlation between transition metal NMR chemical shifts and the stability of coordination compounds
Magazine article, 1996

Linear correlations of transition metal NMR chemical shifts with the logarithm of overall stability constants for six different series of complexes of Co(III), Rh(III), Rh(I) and Pt(II) have been found. Each case is presented and discussed. The relation is interpreted with a simplified version of Ramsey's equation for the chemical shift. A derivation of a relation of the type delta = m - k logK using ligand field theory is proposed.

halide complexes

complexes

alkene complexes

Co-59 NMR spectroscopy

spectroscopy

Pt(II)

complexes

alkylcobaloximes

ligand field

alkylrhodoximes

Rh(III)

platinum(ii)

pr

Pt-195 NMR

pt-195

theory

spectroscopy

stability constants

amine

Co(III)

constants

bond

Rh(I)

(103) NMR spectroscopy

Ramsey's equation

nuclear-magnetic-resonance

Author

Lars Öhrström

Department of Inorganic Chemistry

Other publications Research

Comments on Inorganic Chemistry

Vol. 18 5-6 305-323

Subject Categories

Chemical Sciences

More information

Created

10/8/2017

Feedback and support

If you have questions, need help, find a bug or just want to give us feedback you may use this form, or contact us per e-mail research.lib@chalmers.se.

About

Research.chalmers.se contains research information from Chalmers University of Technology, Sweden. It includes information on projects, publications, research funders and collaborations.

More about coverage period and what is publicly available

Privacy and cookies

Accessibility

Citation Style Language
citeproc-js (Frank Bennett)

Links

Chalmers Library
Chalmers Research
Chalmers Student Theses

Chalmers University of Technology

SE-412 96 GOTHENBURG, SWEDEN
PHONE: +46 (0)31-772 10 00
WWW.CHALMERS.SE