The correlation between transition metal NMR chemical shifts and the stability of coordination compounds
Artikel i övriga tidskrifter, 1996

Linear correlations of transition metal NMR chemical shifts with the logarithm of overall stability constants for six different series of complexes of Co(III), Rh(III), Rh(I) and Pt(II) have been found. Each case is presented and discussed. The relation is interpreted with a simplified version of Ramsey's equation for the chemical shift. A derivation of a relation of the type delta = m - k logK using ligand field theory is proposed.

halide complexes

complexes

alkene complexes

Co-59 NMR spectroscopy

spectroscopy

Pt(II)

complexes

alkylcobaloximes

ligand field

alkylrhodoximes

Rh(III)

platinum(ii)

pr

Pt-195 NMR

pt-195

theory

spectroscopy

stability constants

amine

Co(III)

constants

bond

Rh(I)

(103) NMR spectroscopy

Ramsey's equation

nuclear-magnetic-resonance

Författare

Lars Öhrström

Institutionen för oorganisk kemi

Comments on Inorganic Chemistry

Vol. 18 5-6 305-323

Ämneskategorier

Kemi