The correlation between transition metal NMR chemical shifts and the stability of coordination compounds
Artikel i övriga tidskrifter, 1996
Linear correlations of transition metal NMR chemical shifts with the logarithm of overall stability constants for six different series of complexes of Co(III), Rh(III), Rh(I) and Pt(II) have been found. Each case is presented and discussed. The relation is interpreted with a simplified version of Ramsey's equation for the chemical shift. A derivation of a relation of the type delta = m - k logK using ligand field theory is proposed.
halide complexes
complexes
alkene complexes
Co-59 NMR spectroscopy
spectroscopy
Pt(II)
complexes
alkylcobaloximes
ligand field
alkylrhodoximes
Rh(III)
platinum(ii)
pr
Pt-195 NMR
pt-195
theory
spectroscopy
stability constants
amine
Co(III)
constants
bond
Rh(I)
(103) NMR spectroscopy
Ramsey's equation
nuclear-magnetic-resonance