Investigations of NOx storage catalysts
Journal article, 1998

NOx storage catalysts are used to reduce nitrogen oxides from lean-burn vehicles. The nitrogen oxides are stored in the catalyst during lean conditions and subsequently released and reduced during short periods of rich conditions. In the present study, we systematically investigate the sequence of elementary steps in the NOx reduction cycle, and the extent to which these steps influence the maximum NOx, reduction potential of the catalyst. As a model system, we use barium oxide as the NOx, storing compound in a Pt/Rh/Al2O3 system. Kinetics of NO oxidation, NO and NO2 adsorption, NO and NO2 release and reduction are studied under controlled conditions with systematic variations of temperature, gas composition, and storing/release times. The transient experiments comprise a storing phase using a lean NO/C3H6/O2/N2 gas mixture, and a regenerating phase where the O2 now is turned off. Experimentally, a significant amount of NOx is found to be stored in the Ba-containing material. A maximum in NOx storage is observed around 380 degrees C. For most of the experiments, there are clear NO and NO2 desorption peaks upon switching from the storing to the regeneration phase. TPD studies of NO and NO2 reveal a significant difference between prereduced and pre-oxidised samples where the former produce predominantly N2 and N2O at around 200 degrees C while NO and O2 desorb from the latter around 500 degrees C. In situ FTIR spectra show nitrate peaks in the region 1300-1400 cm(-1) when NOx is stored under lean conditions.

SPECTROSCOPY

ADSORPTION

NITRIC-OXIDE

REDUCTION

TEMPERATURE

CO

OXYGEN

3-WAY CATALYST

Author

Erik Fridell

Chalmers, Applied Physics, Chemical Physics

Competence Centre for Catalysis (KCK)

Magnus Skoglundh

Competence Centre for Catalysis (KCK)

Department of Engineering Chemistry

Stefan Johansson

Competence Centre for Catalysis (KCK)

Chalmers, Applied Physics

Björn Westerberg

Department of Chemical Reaction Engineering

Competence Centre for Catalysis (KCK)

Anders Törncrona

Competence Centre for Catalysis (KCK)

Department of Engineering Chemistry

Gudmund Smedler

Department of Chemical Reaction Engineering

Competence Centre for Catalysis (KCK)

Studies in Surface Science and Catalysis

0167-2991 (ISSN)

Vol. 116 537-547

Driving Forces

Sustainable development

Areas of Advance

Nanoscience and Nanotechnology (2010-2017)

Transport

Energy

Materials Science

Subject Categories

Chemical Engineering

More information

Created

10/7/2017