Entropy-enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
Journal article, 2012
Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors.
pyrene
dna
phantom
sequence specificity
anthracene
calorimetry
binding
thermodynamics
derivatives
Author
Jewgeni Starikow
Chalmers, Chemical and Biological Engineering, Physical Chemistry
Bengt Nordén
Chalmers, Chemical and Biological Engineering, Physical Chemistry
Chemical Physics Letters
0009-2614 (ISSN)
Vol. 538 118-120Areas of Advance
Nanoscience and Nanotechnology
Energy
Life Science Engineering (2010-2018)
Materials Science
Subject Categories (SSIF 2011)
Physical Chemistry
DOI
10.1016/j.cplett.2012.04.028