Entropy-enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
Artikel i vetenskaplig tidskrift, 2012
Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors.
pyrene
dna
phantom
sequence specificity
anthracene
calorimetry
binding
thermodynamics
derivatives
Författare
Jewgeni Starikow
Chalmers, Kemi- och bioteknik, Fysikalisk kemi
Bengt Nordén
Chalmers, Kemi- och bioteknik, Fysikalisk kemi
Chemical Physics Letters
0009-2614 (ISSN)
Vol. 538 118-120Styrkeområden
Nanovetenskap och nanoteknik
Energi
Livsvetenskaper och teknik (2010-2018)
Materialvetenskap
Ämneskategorier (SSIF 2011)
Fysikalisk kemi
DOI
10.1016/j.cplett.2012.04.028