Entropy-enthalpy compensation as a fundamental concept and analysis tool for systematical experimental data
Artikel i vetenskaplig tidskrift, 2012

Enthalpy-entropy compensation (EEC) has a definite physical sense. Here, we review EEC from a new standpoint, using the notion of correlation. The latter has two basic meanings: (a) 'A' is correlated to 'B' means 'A' results from 'B' or vice versa; (b) this same means there is some real, but hidden 'C' in connection to both 'A' and 'B'). In accordance with the interpretation (b), we try rationalizing EEC in terms of hidden, but physically real factors.

sequence specificity

thermodynamics

phantom

binding

derivatives

anthracene

calorimetry

pyrene

dna

Författare

Evgeni B. Starikov

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Bengt Nordén

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Chemical Physics Letters

0009-2614 (ISSN)

Vol. 538 118-120

Styrkeområden

Nanovetenskap och nanoteknik

Energi

Livsvetenskaper och teknik

Materialvetenskap

Ämneskategorier

Fysikalisk kemi

DOI

10.1016/j.cplett.2012.04.028