A missing link between chiral four- and five-coordinate complexes
Journal article, 2015
We report total spontaneous resolution and absolute asymmetric synthesis of [Pd(hfacac)(2)P(o-tol)(3)] (hfacac = hexafluoroacetylacetonate, P(o-tol)(3) = tri(o-tolyl)phosphine), a chiral complex with a coordination geometry intermediate between square-planar, square pyramidal and trigonal bipyramidal.
Resolution
Racemic Crystals
Absolute Asymmetric-Synthesis
Optical
Crystallization
Spontaneous Resolution
Author
Anders Lennartsson
Chalmers, Chemistry and Chemical Engineering, Applied Chemistry
Mikael Håkansson
University of Gothenburg
New Journal of Chemistry
1144-0546 (ISSN) 1369-9261 (eISSN)
Vol. 39 5 3353-3356Subject Categories
Chemical Sciences
DOI
10.1039/c5nj00265f