A missing link between chiral four- and five-coordinate complexes
Journal article, 2015

We report total spontaneous resolution and absolute asymmetric synthesis of [Pd(hfacac)(2)P(o-tol)(3)] (hfacac = hexafluoroacetylacetonate, P(o-tol)(3) = tri(o-tolyl)phosphine), a chiral complex with a coordination geometry intermediate between square-planar, square pyramidal and trigonal bipyramidal.

Resolution

Racemic Crystals

Absolute Asymmetric-Synthesis

Optical

Crystallization

Spontaneous Resolution

Author

Anders Lennartsson

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Polymer Technology

Mikael Håkansson

University of Gothenburg

New Journal of Chemistry

1144-0546 (ISSN) 1369-9261 (eISSN)

Vol. 39 5 3353-3356

Subject Categories

Chemical Sciences

DOI

10.1039/c5nj00265f

More information

Latest update

2/17/2021