Synthesis and Characterization of Fluorodinitroamine, FN(NO2)2.
Journal article, 2014
NF3 and N(NO2)3 are known compds., whereas the mixed fluoronitroamines, FN(NO2)2 and F2NNO2, have been unknown thus far. One of these, FN(NO2)2, has now been prepd. and characterized by multinuclear NMR and Raman spectroscopy. FN(NO2)2 is the first known example of an inorg. fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide anion using NF4+ salts as the preferred fluorinating agent. [on SciFinder(R)]
energetic materials
quantum chemical calculations
fluoronitroamines
dinitramide anion
Author
Karl O. Christe
William W. Wilson
Guillaume Belanger-Chabot
Ralf Haiges
Jerry A. Boatz
Martin Rahm
G. K. Surya Prakash
Thomas Saal
Mathias. Hopfinger
Angewandte Chemie - International Edition
1433-7851 (ISSN) 1521-3773 (eISSN)
Vol. 54 1316-1320Subject Categories
Inorganic Chemistry
Materials Chemistry
Theoretical Chemistry
DOI
10.1002/anie.201410507