Synthesis and Characterization of Fluorodinitroamine, FN(NO2)2.
Artikel i vetenskaplig tidskrift, 2014

NF3 and N(NO2)3 are known compds., whereas the mixed fluoronitroamines, FN(NO2)2 and F2NNO2, have been unknown thus far. One of these, FN(NO2)2, has now been prepd. and characterized by multinuclear NMR and Raman spectroscopy. FN(NO2)2 is the first known example of an inorg. fluoronitroamine. It is a thermally unstable, highly energetic material formed by the fluorination of the dinitramide anion using NF4+ salts as the preferred fluorinating agent. [on SciFinder(R)]

energetic materials

quantum chemical calculations

fluoronitroamines

dinitramide anion

Författare

Karl O. Christe

William W. Wilson

Guillaume Belanger-Chabot

Ralf Haiges

Jerry A. Boatz

G. K. Surya Prakash

Thomas Saal

Mathias. Hopfinger

Angewandte Chemie - International Edition

1433-7851 (ISSN) 1521-3773 (eISSN)

Vol. 54 1316-1320

Ämneskategorier

Oorganisk kemi

Materialkemi

Teoretisk kemi

DOI

10.1002/anie.201410507