Syntheses of Diphenylaminodiazidophosphane and Diphenylaminofluoroazidophosphane

Journal article, 2015

Diphenylaminodiazidophosphane (C6H5)2NP(N3)2 was synthesized from the corresponding dihalides (C6H5)2NPX2 (X = F, Cl) and (CH3)3SiN3. The new compound was characterized by vibrational as well as multinuclear NMR spectroscopy, and some of its physical properties are reported. The intermediate compound (C6H5)2NPF(N3) was observed by NMR spectroscopy. Vibrational and NMR data of (C6H5)2NPX2 (X = F,Cl) are also reported.