Syntheses of Diphenylaminodiazidophosphane and Diphenylaminofluoroazidophosphane
Artikel i vetenskaplig tidskrift, 2015

Diphenylaminodiazidophosphane (C6H5)2NP(N3)2 was synthesized from the corresponding dihalides (C6H5)2NPX2 (X = F, Cl) and (CH3)3SiN3. The new compound was characterized by vibrational as well as multinuclear NMR spectroscopy, and some of its physical properties are reported. The intermediate compound (C6H5)2NPF(N3) was observed by NMR spectroscopy. Vibrational and NMR data of (C6H5)2NPX2 (X = F,Cl) are also reported.

azides

inorganic synthesis

energetic materials

density functional theory

Författare

W Wilson

A. J. Clough

R Haiges

K. O. Christe

Inorganic Chemistry

0020-1669 (ISSN) 1520-510X (eISSN)

Vol. 54 11859-11867

Ämneskategorier

Oorganisk kemi

Teoretisk kemi

DOI

10.1021/acs.inorgchem.5b02097