Supramolecular Control in Carbohydrate Epimerization: Discovery of a New Anion Host-Guest System.
Journal article, 2008
A new anion-carbohydrate recognition system is described. Pyranosides with axial protons in 1-, 3-, and 5-position proved efficient, forming relatively strong complexes between the anion and the B-face of the carbohydrate. This system could furthermore be used in supramol. control in Lattrell-Dax epimerization reactions, leading to either activation or deactivation effects. [on SciFinder(R)]
Solvent effects
nitrite chemistry
density functional theory
Epimerization catalysts
host guest chemistry
Author
Hai Dong
Martin Rahm
Tore Brinck
Olof. Ramstroem
Journal of the American Chemical Society
0002-7863 (ISSN) 1520-5126 (eISSN)
Vol. 130 46 15270-15271Subject Categories
Theoretical Chemistry
Organic Chemistry
DOI
10.1021/ja807044p