Supramolecular Control in Carbohydrate Epimerization: Discovery of a New Anion Host-Guest System.
Artikel i vetenskaplig tidskrift, 2008

A new anion-carbohydrate recognition system is described. Pyranosides with axial protons in 1-, 3-, and 5-position proved efficient, forming relatively strong complexes between the anion and the B-face of the carbohydrate. This system could furthermore be used in supramol. control in Lattrell-Dax epimerization reactions, leading to either activation or deactivation effects. [on SciFinder(R)]

Solvent effects

nitrite chemistry

density functional theory

Epimerization catalysts

host guest chemistry

Författare

Hai Dong

Tore Brinck

Olof. Ramstroem

Journal of the American Chemical Society

0002-7863 (ISSN) 1520-5126 (eISSN)

Vol. 130 15270-15271

Ämneskategorier

Teoretisk kemi

Organisk kemi

DOI

10.1021/ja807044p