The effect of rosin acid on hydrodeoxygenation of fatty acid
Journal article, 2019

In this study, inhibition of tall oil fatty acid hydrodeoxygenation (HDO) activity due to addition of rosin acid over sulfided NiMo/Al2O3 was investigated. Oleic acid and abietic acid were used as model compounds for fatty acid and rosin acid respectively in tall oil. After completion of each HDO experiment, the NiMo catalysts were recovered and used again under the same conditions. The results showed that the oleic acid HDO activity of sulfided catalysts was inhibited by addition of abietic acid due to competitive adsorption and increased coke deposition. The rate of carbon deposition on the catalysts increased when abietic acid was added to oleic acid feed. Moreover, the coke was in a more advanced form with higher stability for the catalysts exposed to both oleic acid and abietic acid. Furthermore, a clear correlation between the rate of coke formation and concentration of abietic acid was observed.

Inhibition

Carbon deposition

Rosin acid

Hydrodeoxygenation (HDO)

Coke formation

Author

Houman Ojagh

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Competence Centre for Catalysis (KCK)

Derek Creaser

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Competence Centre for Catalysis (KCK)

Muhammad Abdus Salam

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Competence Centre for Catalysis (KCK)

Eva Lind Grennfelt

Preem

Louise Olsson

Chalmers, Chemistry and Chemical Engineering, Chemical Technology

Competence Centre for Catalysis (KCK)

Journal of Energy Chemistry

2095-4956 (ISSN)

Vol. 28 85-94

The Competence Centre for Catalysis, KCK

ECAPS AB, 2018-01-01 -- 2021-12-31.

Chalmers, 2018-01-01 -- 2021-12-31.

Johnson Matthey AB, 2018-01-01 -- 2021-12-31.

Volvo Car Corporation, 2018-01-01 -- 2021-12-31.

Scania CV AB, 2018-01-01 -- 2021-12-31.

Umicore AG & Co KG, 2018-01-01 -- 2021-12-31.

Swedish Energy Agency, 2018-01-01 -- 2021-12-31.

Preem, 2018-01-01 -- 2021-12-31.

Volvo Group, 2018-01-01 -- 2021-12-31.

Areas of Advance

Energy

Subject Categories

Other Chemical Engineering

Other Chemistry Topics

Organic Chemistry

DOI

10.1016/j.jechem.2018.01.023

More information

Latest update

3/3/2019 1