Methane adsorption and methanol desorption of copper modified boron silicate
Journal article, 2018

Boron silicate (BS) with a chabazite framework structure was synthesised using a direct route and rigorously characterized before it was ion-exchanged with copper to form Cu-BS. Employing in situ infrared spectroscopy, we show that Cu-BS is capable of oxidising methane to methoxy species and methanol interacts with the boron sites without deprotonation.

Methane adsorption

Methoxy species

Situ infrared spectroscopy

Ion exchange

Methanol

Zeolites

Copper compounds

Solicates

Infrared spectroscopy

Synthesised

Methane

Framework structures

Author

Xueting Wang

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Applied Surface Chemistry

Alexander Shishkin

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Applied Surface Chemistry

Felix Hemmingsson

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Per-Anders Carlsson Group

Magnus Skoglundh

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Polymer Technology

F. J. Martinez-Casado

Lund University

Lorenz Bock

Alexander Idström

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Applied Surface Chemistry

Lars Nordstierna

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Lars Nordstierna Group

Hanna Härelind

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Pharmaceutical Technology

Per-Anders Carlsson

Chalmers, Chemistry and Chemical Engineering, Applied Chemistry, Per-Anders Carlsson Group

RSC Advances

2046-2069 (ISSN)

Vol. 8 63 36369-36374

Subject Categories

Inorganic Chemistry

DOI

10.1039/c8ra08038k

More information

Latest update

11/25/2018