Visible-Light-Driven Stereoselective Annulation of Alkyl Anilines and Dibenzoylethylenes via Electron Donor-Acceptor Complexes
Journal article, 2021

A catalyst-free, stereoselective visible-light-driven annulation reaction between alkenes and N,N-substituted dialkyl anilines for the synthesis of substituted tetrahydroquinolines is presented. The reaction is driven by the photoexcitation of an electron donor-acceptor (EDA) complex, and the resulting products are obtained in good to high yields with complete diastereoselectivity. Mechanistic rationale and photochemical characterization of the EDA-complex are provided.

Author

August Runemark

Chalmers, Chemistry and Chemical Engineering, Chemistry and Biochemistry, Physical Chemistry

Savannah C. Zacharias

University of Gothenburg

Henrik Sundén

University of Gothenburg

Chalmers, Chemistry and Chemical Engineering, Chemistry and Biochemistry

Journal of Organic Chemistry

0022-3263 (ISSN) 1520-6904 (eISSN)

Vol. 86 2 1901-1910

Singlet fission in self-assembly materials

Formas, 2020-01-01 -- 2022-12-31.

Subject Categories

Organic Chemistry

DOI

10.1021/acs.joc.0c02819

PubMed

33397115

More information

Latest update

2/12/2021