Visible-Light-Driven Stereoselective Annulation of Alkyl Anilines and Dibenzoylethylenes via Electron Donor-Acceptor Complexes
Artikel i vetenskaplig tidskrift, 2021

A catalyst-free, stereoselective visible-light-driven annulation reaction between alkenes and N,N-substituted dialkyl anilines for the synthesis of substituted tetrahydroquinolines is presented. The reaction is driven by the photoexcitation of an electron donor-acceptor (EDA) complex, and the resulting products are obtained in good to high yields with complete diastereoselectivity. Mechanistic rationale and photochemical characterization of the EDA-complex are provided.

Författare

August Runemark

Chalmers, Kemi och kemiteknik, Kemi och biokemi, Fysikalisk kemi

Savannah C. Zacharias

Göteborgs universitet

Henrik Sundén

Göteborgs universitet

Chalmers, Kemi och kemiteknik, Kemi och biokemi

Journal of Organic Chemistry

0022-3263 (ISSN) 1520-6904 (eISSN)

Vol. 86 2 1901-1910

Effektivare solceller med singlettfission i självbyggande material

Formas, 2020-01-01 -- 2022-12-31.

Ämneskategorier

Organisk kemi

DOI

10.1021/acs.joc.0c02819

Mer information

Senast uppdaterat

2021-02-12