Visible-Light-Driven Stereoselective Annulation of Alkyl Anilines and Dibenzoylethylenes via Electron Donor-Acceptor Complexes
Artikel i vetenskaplig tidskrift, 2021
A catalyst-free, stereoselective visible-light-driven annulation reaction between alkenes and N,N-substituted dialkyl anilines for the synthesis of substituted tetrahydroquinolines is presented. The reaction is driven by the photoexcitation of an electron donor-acceptor (EDA) complex, and the resulting products are obtained in good to high yields with complete diastereoselectivity. Mechanistic rationale and photochemical characterization of the EDA-complex are provided.
Författare
August Runemark
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Savannah C. Zacharias
Göteborgs universitet
Henrik Sundén
Göteborgs universitet
Chalmers, Kemi och kemiteknik, Kemi och biokemi
Journal of Organic Chemistry
0022-3263 (ISSN) 1520-6904 (eISSN)
Vol. 86 2 1901-1910Effektivare solceller med singlettfission i självbyggande material
Formas (2019-00699), 2020-01-01 -- 2022-12-31.
Ämneskategorier
Organisk kemi
DOI
10.1021/acs.joc.0c02819
PubMed
33397115