Oxygen carrier aided combustion (OCAC) of two waste fuels - Experimental and theoretical study of the interaction between ilmenite and zinc, copper and lead
Journal article, 2021

Zinc, copper and lead are amongst the more abundant trace metals in waste fuels such as municipal solid waste and recovered waste wood. The ashes from waste fuels could contain high contents of these metals, which could be valuable but also toxic in certain environments. Oxygen carrier aided combustion, OCAC, is a novel technology for combustion of biomass and waste. Utilizing oxygen carriers could affect the fate of these metals and have implications for stability and recycling. The aim of this work is to study the fate of zinc, copper and lead during oxygen carrier aided combustion of two waste fuels utilizing ilmenite as an oxygen carrier. In total, four samples have been obtained from two different industrial fluidized bed boilers using ilmenite as bed material. Due to low concentrations, bulk analysis methods are not suitable for speciation, i.e. SEM/EDX and XRD. Hence, this investigation utilizes high resolution x-ray photoelectron spectroscopy (XPS), coupled to detailed thermodynamic modelling, with the aim of understanding trace metal speciation, distribution and phase composition. Characterization of the four samples show that iron at the surface of ilmenite particles interact with both copper and zinc to form ferrites, CuFe O and ZnFe O . Lead, on the other hand, is more prone to end up in the fly ash as condensed PbCl , but the mixed oxide PbTiO could be identified at the oxygen carrier surface. Thermodynamic calculations were shown to be in line with the identified compounds.

Recovered waste wood (RWW)

Ilmenite

Oxygen carrier aided combustion (OCAC)

Oxygen carrier

Municipal solid waste (MSW)

X-ray photoelectron spectroscopy (XPS)

Author

Ivana Stanicic

Chalmers, Space, Earth and Environment, Energy Technology, Energy Technology 2

Tobias Mattisson

Chalmers, Space, Earth and Environment, Energy Technology

R. Backman

Umeå University

Yu Cao

Chalmers, Industrial and Materials Science, Materials and manufacture

Magnus Rydén

Chalmers, Space, Earth and Environment, Energy Technology

Biomass and Bioenergy

0961-9534 (ISSN)

Vol. 148 106060

Oxygen Carrier Aided Combustion for more efficient fuel conversion in FB plants with simultaneous recovery of alkali compounds

Swedish Energy Agency, 2018-06-01 -- 2021-12-31.

Subject Categories

Other Chemistry Topics

Bioenergy

Corrosion Engineering

DOI

10.1016/j.biombioe.2021.106060

More information

Latest update

4/27/2021