Trends, composition, and sources of carbonaceous aerosol at the Birkenes Observatory, northern Europe, 2001-2018
Journal article, 2021

We present 18 years (2001-2018) of aerosol measurements, including organic and elemental carbon (OC and EC), organic tracers (levoglucosan, arabitol, mannitol, trehalose, glucose, and 2-methyltetrols), trace elements, and ions, at the Birkenes Observatory (southern Norway) - a site representative of the northern European region. The OC=EC (2001-2018) and the levoglucosan (2008-2018) time series are the longest in Europe, with OC=EC available for the PM10, PM2:5 (fine), and PM10-2:5 (coarse) size fractions, providing the opportunity for a nearly 2-decade-long assessment. Using positive matrix factorization (PMF), we identify seven carbonaceous aerosol sources at Birkenes: mineraldust- dominated aerosol (MIN), traffic/industry-like aerosol (TRA/IND), short-range-transported biogenic secondary organic aerosol (BSOASRT), primary biological aerosol particles (PBAP), biomass burning aerosol (BB), ammoniumnitrate- dominated aerosol (NH4NO3), and (one low carbon fraction) sea salt aerosol (SS). We observed significant (p < 0:05), large decreases in EC in PM10 (-3:9%yr-1) and PM2:5 (-4:2%yr-1) and a smaller decline in levoglucosan (-2:8%yr-1), suggesting that OC=EC from traffic and industry is decreasing, whereas the abatement of OC=EC from biomass burning has been slightly less successful. EC abatement with respect to anthropogenic sources is further supported by decreasing EC fractions in PM2:5 (-3:9%yr-1) and PM10 (-4:5%yr-1). PMF apportioned 72% of EC to fossil fuel sources; this was further supported by PMF applied to absorption photometer data, which yielded a two-factor solution with a low aerosol ngstr m exponent (AAED0.93) fraction, assumed to be equivalent black carbon from fossil fuel combustion (eBCFF), contributing 78% to eBC mass. The higher AAE fraction (AAED2.04) is likely eBC from BB (eBCBB). Source-receptor model calculations (FLEXPART) showed that continental Europe and western Russia were the main source regions of both elevated eBCBB and eBCFF. Dominating biogenic sources explain why there was no downward trend for OC. A relative increase in the OC fraction in PM2:5 (C3:2%yr-1) and PM10 (C2:4%yr-1) underscores the importance of biogenic sources at Birkenes (BSOA and PBAP), which were higher in the vegetative season and dominated both fine (53 %) and coarse (78 %) OC. Furthermore, 77 %-91% of OC in PM2:5, PM10-2:5, and PM10 was attributed to biogenic sources in summer vs. 22 %- 37% in winter. The coarse fraction had the highest share of biogenic sources regardless of season and was dominated by PBAP, except in winter. Our results show a shift in the aerosol composition at Birkenes and, thus, also in the relative source contributions. The need for diverse offline and online carbonaceous aerosol speciation to understand carbonaceous aerosol sources, including their seasonal, annual, and long-term variability, has been demonstrated.

Author

Karl Espen Yttri

Norwegian Institute for Air Research (NILU)

Francesco Canonaco

Datalystica Ltd.

Paul Scherrer Institut

S. Eckhardt

Norwegian Institute for Air Research (NILU)

Nikolaos Evangeliou

Norwegian Institute for Air Research (NILU)

Markus Fiebig

Norwegian Institute for Air Research (NILU)

Hans Gundersen

Norwegian Institute for Air Research (NILU)

Anne Gunn Hjellbrekke

Norwegian Institute for Air Research (NILU)

Cathrine Lund Myhre

Norwegian Institute for Air Research (NILU)

Stephen Matthew Platt

Norwegian Institute for Air Research (NILU)

A.S.H. Prevot

Paul Scherrer Institut

David Simpson

Chalmers, Space, Earth and Environment, Microwave and Optical Remote Sensing

Norwegian Meteorological Institute

S. Solberg

Norwegian Institute for Air Research (NILU)

J. D. Surratt

The University of North Carolina at Chapel Hill

K. Torseth

Norwegian Institute for Air Research (NILU)

Hilde Uggerud

Norwegian Institute for Air Research (NILU)

Marit Vadset

Norwegian Institute for Air Research (NILU)

Xin Wan

Chinese Academy of Sciences

Wenche Aas

Norwegian Institute for Air Research (NILU)

Atmospheric Chemistry and Physics

1680-7316 (ISSN) 1680-7324 (eISSN)

Vol. 21 9 7149-7170

Subject Categories

Meteorology and Atmospheric Sciences

Other Earth and Related Environmental Sciences

Physical Geography

DOI

10.5194/acp-21-7149-2021

More information

Latest update

5/28/2021