Reactivity of Mixed Layer Clays – The Effect of Polycarboxylate Based Superplasticizers on Effective Particle Size Distributions

Paper in proceeding, 2023

The declining availability of promising supplementary cementitious materials (SCMs) in the recent past, such as fly ash and ggbfs, has opened new recesses in the domain of alternative binders. It is therefore imperative and urgent to develop more lasting and consistent alternatives, for addressing the need to diminish the carbon footprint of cement production. The potentialities of utilizing mixed layer excavated clays that are obtained as by-products of repair and construction activities, as possible SCMs have been well established in past literature. However, understanding the relationship between particle deagglomeration and pozzolanic properties via non-energy-intensive methods, is still an open niche yet to be fully explored. This study is an attempt at understanding the use of dispersive mechanisms such as super-plasticizers and storage in suspension to possibly impact surface charges of clay agglomerates and eventually, their reactivity. It is found that dispersive agents added to ground clay particles can enhance pozzolanicity of mixed layer clay particles and thereby reduce dependence on energy intensive methods such as grinding for activation.