A ferromagnetic Eu-Pt surface compound grown below hexagonal boron nitride
Journal article, 2023

One of the fundamental applications for monolayer-thick 2D materials is their use as protective layers of metal surfaces and in situ intercalated reactive materials in ambient conditions. Here we investigate the structural, electronic, and magnetic properties, as well as the chemical stability in air of a very reactive metal, Europium, after intercalation between a hexagonal boron nitride (hBN) layer and a Pt substrate. We demonstrate that Eu intercalation leads to a hBN-covered ferromagnetic EuPt2 surface alloy with divalent Eu2+ atoms at the interface. We expose the system to ambient conditions and find a partial conservation of the di-valent signal and hence the Eu-Pt interface. The use of a curved Pt substrate allows us to explore the changes in the Eu valence state and the ambient pressure protection at different substrate planes. The interfacial EuPt2 surface alloy formation remains the same, but the resistance of the protecting hBN layer to ambient conditions is reduced, likely due to a rougher surface and a more discontinuous hBN coating.

Author

Alaa Mohammed Idris Bakhit

Centro de Física de Materiales (CSIC-UPV/EHU)

University of the Basque Country (UPV/EHU)

Khadiza Ali

Donostia International Physics Center

Chalmers, Microtechnology and Nanoscience (MC2), Quantum Device Physics

Anna A. Makarova

Freie Universität Berlin

Igor Píš

Laboratorio Nazionale TASC

Federica Bondino

Laboratorio Nazionale TASC

Roberto Sant

European Synchrotron Radiation Facility (ESRF)

Saroj Prasad Dash

Chalmers, Microtechnology and Nanoscience (MC2), Quantum Device Physics

R. Castrillo-Bodero

Centro de Física de Materiales (CSIC-UPV/EHU)

Yuri Hasegawa

Centro de Física de Materiales (CSIC-UPV/EHU)

College of Life Sciences

J. E. Ortega

Centro de Física de Materiales (CSIC-UPV/EHU)

University of the Basque Country (UPV/EHU)

Donostia International Physics Center

L. Fernandez

Centro de Física de Materiales (CSIC-UPV/EHU)

F. Schiller

Centro de Física de Materiales (CSIC-UPV/EHU)

Donostia International Physics Center

Nanoscale

2040-3364 (ISSN) 20403372 (eISSN)

Vol. 15 27 11517-11528

Subject Categories

Condensed Matter Physics

DOI

10.1039/d3nr00630a

More information

Latest update

7/20/2023