Fluidized bed plants for heat and power production in future energy systems

Doctoral thesis, 2023

Fluidized bed (FB) plants are used for heat and power production in several energy systems around the world, with particular importance in systems using large shares of renewable solid fuel, e.g., biomass. These FB plants are traditionally operated for base-load electricity production or for heat production, and thus characterized by relatively small and slow load changes. In parallel, as the transition towards energy systems with net-zero emissions increases the share of variable renewable energy (VRE) sources, the need for implementing variation management strategies at various timescales arises – giving heat and power plants the possibility to adapt their operations to accommodate the inherent variability of VRE sources. Following this, FB technology is envisioned for a wide range of novel applications expected to play significant roles in the decarbonization of energy systems, such as thermochemical energy storage and carbon capture and storage. In this context, research efforts are needed to investigate the technical and economic features of FB plants in energy systems with high levels of VRE.
The aim of this thesis is to elucidate the capabilities of FB plants for heat and power production in net-zero emissions energy systems. For this purpose, two main pathways are explored: i) transient operation as fuel-fed plants, and ii) the potential conversion into decarbonized plants, i.e., into VRE-fed layouts providing dispatchable outputs.
For fuel-fed FB plants, a dynamic model of biomass-fired FB plants has been developed, considering the two types of FB boilers (BFB and CFB) and including validation against steady-state and transient operational data collected from two commercial plants. As a novelty of this work the model describes both the gas (in-furnace) and water-steam sides such that the interactions between the two can be assessed. The results of the simulations show that i) the characteristic times for the gas side are shorter in BFB furnaces than in CFBs, albeit these times are for both furnace types not longer than those for the water-steam side; ii) the computed timescales for the dynamics of FB plants fall well within those required for offering complementing services to the grid; and iii) the use of control and operational strategies for the water-steam side can confer capabilities superior to fuel-feeding control in terms of avoiding undesirable unburnt emissions and providing temporary overload operation. The retrofit of fuel-fed FB plants into poly-generation facilities cogenerating a combustible biogenic gas is also assessed, revealing that partial combustion of this gas can be used to provide faster inherent dynamics than the original configuration.
For VRE-fed FB layouts, techno-economic process modeling has been carried out for large-scale deployment of solar- and electricity-charging processes based on three different chemical systems: i) carbonation/calcination (calcium); ii) thermally reduced redox (cobalt oxides); and iii) chemically reduced redox (iron oxides). One attractive aspect of these layouts is the possibility to build part of them by retrofitting current fuel-fed FB plants. While the technical assessment for solar applications indicates that cobalt-based layouts offer the highest levels of efficiency and dispatchability, calcium-based processes present better economics owing to the use of inexpensive calcium material. The results also show that electricity-charged layouts such as iron looping can play an important role in the system providing variation management strategies to the grid while avoiding costly H2 storage. Further, the economic performances of VRE-fed FB layouts are benefitted by the generation of additional services and products (e.g., carbon capture and on-demand production of H2), and by scenarios with high volatility of the electricity prices.