Recycling of Steel Grinding Swarf via Production of Iron Chloride Coagulants for Water Treatment
Licentiate thesis, 2024
Since steel grinding swarf predominantly consists of iron, the aim of this thesis was to investigate whether it could be used as raw material in production of iron based coagulants for water treatment. Hydrometallurgy was used to extract iron from swarf by leaching with hydrochloric acid and separating the formed iron chloride solution from metal impurities by precipitation and filtration. Each step of the process was designed and optimized to find simple yet flexible solutions to make the recycling process economically feasible, and capable of handling variations in the grinding swarf.
A two-step method was proposed based on completely dissolving iron in the swarf at 60°C and pH ≤2 for 3 h, and thereafter reducing the acid concentration to pH 4 for 1 h to precipitate any leached impurities. This guarantees complete separation of Al, Cr and Mo from the solution by hydrolysis, and can to a large extent also remove Co, Cu and Ni by cementation. Lubricating oils are flocculated by solids in the slurry and can therefore also be removed by filtration.
A 3.8 M FeCl2 solution was produced which conformed to the highest purity standards for drinking water coagulants and was considered to be a good precursor for FeCl3 production. Around 30 kg hydrogen gas are also generated per ton of swarf recycled which can provide additional value in recycling if captured. Besides these products, the process also generated solid leaching residues which were determined to have potential application in high alloy steel production.
Water Treatment
Ferric Chloride
Hazardous waste
Leaching
Hydrometallurgy
Author
Thomas Ottink
Chalmers, Chemistry and Chemical Engineering, Energy and Material
Novel approach to recycling of steel swarf using hydrometallurgy
Resources, Conservation and Recycling,;Vol. 185(2022)
Journal article
Ottink, T., Petranikova, M. Recycling of Steel Grinding Swarf via Production of High Purity Iron Chloride Coagulants and Hydrogen Gas
Subject Categories
Inorganic Chemistry
Chemical Process Engineering
Metallurgy and Metallic Materials
Corrosion Engineering
Driving Forces
Sustainable development
Innovation and entrepreneurship
Areas of Advance
Production
Infrastructure
Chalmers Materials Analysis Laboratory
Licentiatuppsatser vid Institutionen för kemi och kemiteknik, Chalmers tekniska högskola: Technical report no 2024:02
Publisher
Chalmers
10:an, Kemigården 4, Chalmers
Opponent: Mari Lundström, Department of Chemical and Metallurgical Engineering, Aalto University, Finland