Bis(1,3,5-triazine-2,4,6-triamine-κN1)silver(I) nitrate
Journal article, 2009

The title compound, [Ag(C3H6N6)2]NO3, has an alternating two-dimensional bilayer structure supported by extensive hydrogen bonds. The [Ag(melamine)2]+ cationic monomers (melamine is 1,3,5-triazine-2,4,6-triamine) are connected via N—H...N hydrogen bonds to form two-dimensional sheets. Nitrate groups are sandwiched between two sheets through N—H...O hydrogen bonds. An almost perfectly linear coordination geometry is found for the AgI ions. The triazine ligands are slightly distorted due to π–π interactions.

hydrogen bonds


X-ray structure determination

2D structure


Al-Shimaà A A Massoud

Chalmers, Chemical and Biological Engineering, Physical Chemistry

Vratislav Langer

Chalmers, Chemical and Biological Engineering, Environmental Inorganic Chemistry

Acta Crystallographica Section C: Crystal Structure Communications

0108-2701 (ISSN) 1600-5759 (eISSN)

Vol. C65 5 m198-m200

Subject Categories

Inorganic Chemistry

Physical Chemistry



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