Bis(1,3,5-triazine-2,4,6-triamine-κN1)silver(I) nitrate
Artikel i vetenskaplig tidskrift, 2009

The title compound, [Ag(C3H6N6)2]NO3, has an alternating two-dimensional bilayer structure supported by extensive hydrogen bonds. The [Ag(melamine)2]+ cationic monomers (melamine is 1,3,5-triazine-2,4,6-triamine) are connected via N—H...N hydrogen bonds to form two-dimensional sheets. Nitrate groups are sandwiched between two sheets through N—H...O hydrogen bonds. An almost perfectly linear coordination geometry is found for the AgI ions. The triazine ligands are slightly distorted due to π–π interactions.

hydrogen bonds

coordination

X-ray structure determination

2D structure

Författare

Al-Shimaà A A Massoud

Chalmers, Kemi- och bioteknik, Fysikalisk kemi

Vratislav Langer

Chalmers, Kemi- och bioteknik, Oorganisk miljökemi

Acta Crystallographica Section C: Crystal Structure Communications

0108-2701 (ISSN) 1600-5759 (eISSN)

Vol. C65 5 m198-m200

Ämneskategorier

Oorganisk kemi

Fysikalisk kemi

DOI

10.1107/S0108270109013110

Mer information

Skapat

2017-10-06