Formation of organic iodides from containment paint ingredients caused by gamma irradiation
Journal article, 2013

The formation of volatile alkyl iodides other than methyl iodide during a serious nuclear reactor accident may have radiological significance. The hypothesis that radioactive alkyl iodides, other than methyl iodide, could form from paint solvents under the conditions of a serious nuclear accident in light water reactors (under boiling water reactor (BWR) and pressurised water reactor (PWR) conditions) was tested using stable elemental iodine, a gamma irradiator and gas chromatography equipment. It was found that methyl and isopropyl iodides were formed from the texanol ester, which is used in many modern water-based paints. Methyl, ethyl, propyl and butyl iodides were formed from a hydrocarbon solvent (white spirit) commonly used in paint products used in the past. These results suggest that further work on the formation and behaviour of the higher alkyl iodides (containing more than one carbon atom) under the conditions of a serious nuclear accident is justified.

severe nuclear accidents

texanol ester

accident conditions

nuclear

radiolysis

white spirit

efficiency

paint solvents

containment

iodine

Author

Sabrina Tietze

Chalmers, Chemical and Biological Engineering, Nuclear Chemistry

Mark Foreman

Chalmers, Chemical and Biological Engineering, Nuclear Chemistry

Christian Ekberg

Chalmers, Chemical and Biological Engineering, Nuclear Chemistry

Journal of Nuclear Science and Technology

0022-3131 (ISSN)

Vol. 50 7 689-694

Subject Categories

Inorganic Chemistry

Subatomic Physics

DOI

10.1080/00223131.2013.799400

More information

Latest update

5/21/2024