Chemical deactivation by phosphorous under lean hydrothermal conditions over Cu/BEA NH3-SCR catalysts
Journal article, 2014

To obtain a better understanding of the deactivation of SCR catalysts that may be encountered due to the presence of P-containing impurities in diesel exhausts, the effects induced by P over Cu/BEA NH3-SCR catalysts were studied as functions of the temperature of poisoning and P concentration in the feed. Cu/BEA catalysts with different Cu loadings (4 and 1.3 wt% Cu) were exposed to P by controlled evaporation of H3PO4 in the presence of 8% O2 and 5% H2O at 573 and 773 K. The reaction studies were performed by NH3-storage/TPD, NH3/NO oxidation and standard NH3-SCR. In addition, a combination of several characterisation techniques (ICP–AES, BET surface area, pore size distribution, H2-TPR and XPS) was applied to provide useful information regarding the mechanism of P deactivation. Pore condensation of H3PO4 in combination with pore blocking was observed. However, the measured overall deactivation was found to occur mostly by chemical deactivation reducing the number of the active Cu species and hence deteriorating the redox properties of the Cu/BEA catalysts. The process of P accumulation on the surface preferentially occurs on the “over exchanged” Cu active sites with the formation of phosphate species. This is likely the reason for the more severe deactivation of the 4% Cu/BEA compared to 1.3% Cu/BEA. Further, the higher NOx reduction performance at 773 K of the P-poisoned Cu/BEA catalysts was found to originate from the lower selectivity towards NH3 oxidation, which occurs predominately on the “over-exchanged” sites.

Deactivation

Cu/BEA catalysts

P poisoning

NOx reduction

NH3 SCR

Author

Stanislava Andonova

Chalmers, Chemical and Biological Engineering, Chemical Reaction Engineering

Competence Centre for Catalysis (KCK)

Evgeny Vovk

Bilkent Universitesi

Russian Academy of Sciences

Jonas Sjöblom

Chalmers, Applied Mechanics, Combustion

Emrah Ozensoy

Bilkent Universitesi

Louise Olsson

Chalmers, Chemical and Biological Engineering, Chemical Reaction Engineering

Competence Centre for Catalysis (KCK)

Applied Catalysis B: Environmental

0926-3373 (ISSN) 1873-3883 (eISSN)

Vol. 147 251-263

Areas of Advance

Transport

Subject Categories

Chemical Process Engineering

Chemical Engineering

DOI

10.1016/j.apcatb.2013.08.041

More information

Latest update

6/11/2018