Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes
Journal article, 2019
A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S',S''-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S',S''-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].
Author
Mark Foreman
Chalmers, Chemistry and Chemical Engineering, Energy and Material
Anthony F. Hill
Australian National University
Chenxi Ma
Australian National University
Never Tshabang
Australian National University
University of Botswana
Andrew J.P. White
Imperial College London
Dalton Transactions
1477-9226 (ISSN) 1477-9234 (eISSN)
Vol. 48 1 209-219Subject Categories
Inorganic Chemistry
Theoretical Chemistry
Organic Chemistry
DOI
10.1039/c8dt04278k
PubMed
30516190