Evaluation of NOx-Reduction Measures for Iron-Ore Rotary Kilns
Journal article, 2020

The grate-kiln process is employed for sintering and oxidation of iron-ore pellets. In this process, a fuel (typically coal) is combusted with a large amount of excess air in a rotary kiln, and the high air-to-fuel ratio leads to significant NOx formation. The current Article is an assessment of NOx reduction measures that have been tested in pilot-scale and in full-scale by the Swedish iron-ore company Luossavaara-Kiirunavaara Aktiebolag (LKAB). The results show that the scaling between the full-scale kiln and the pilot-scale kiln is crucial, and several primary measures that reduce NOx significantly in pilot-scale achieve negligible reduction in full-scale. In the investigated full-scale kiln, thermal NOx formation is efficiently suppressed and low compared with the NO formation from the fuel-bound nitrogen (especially char-bound nitrogen). Suppressing the NO formation from the char-bound nitrogen is difficult due to the high amounts of excess air, and all measures tested to alter mixing patterns have shown limited effect. Switching to a fuel with a lower nitrogen content is efficient and probably necessary to achieve low NOx emissions without secondary measures. Simulations show that replacing the reference coal with a biomass that contains 0.1% nitrogen can reduce NOx emissions by 90%.

Author

Rikard Edland

Chalmers, Space, Earth and Environment, Energy Technology

Neil Smith

University of Adelaide

Thomas Allgurén

Chalmers, Space, Earth and Environment, Energy Technology, Energy Technology 2

Christian Fredriksson

LKAB

Fredrik Normann

Chalmers, Space, Earth and Environment, Energy Technology

Denver Haycock

Brigham Young University

Colson Johnson

Texas A&M University

Jacob Frandsen

Brigham Young University

Tom Fletcher

Brigham Young University

Klas Andersson

Chalmers, Space, Earth and Environment, Energy Technology

Energy & Fuels

0887-0624 (ISSN) 1520-5029 (eISSN)

Vol. 34 4 4934-4948

Reduced CO2 emissions from LKABs rotary kiln process – a study of the effect of alternative fuels

LKAB, 2013-05-01 -- 2016-04-30.

Swedish Energy Agency, 2013-05-01 -- 2016-04-30.

Driving Forces

Sustainable development

Subject Categories

Energy Engineering

Areas of Advance

Energy

DOI

10.1021/acs.energyfuels.9b04091

More information

Latest update

7/3/2020 6