Phosphitylation and quantitative P-31 NMR analysis of partially substituted biodiesel glycerols
Artikel i vetenskaplig tidskrift, 2009

The main step during biodiesel production is the catalytic transesterification of triglycerides. Glycerol and fatty acids are by-products of the biodiesel production and considered as contaminants in the final product. By selectively measuring the amount of fatty acids and glycerol with different substitution levels, the yield of this step and the quality of the final biodiesel can be determined. This study examines the application of phosphitylation of glycerol hydroxyl groups with 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane followed by P-31 NMR analysis to provide a rapid quantitative analytical technique for the determination of substitution patterns on partially esterified glycerols, alcohols and the detection of fatty acids. P-31 NMR chemical shift data was established with a series mono and di-substituted esters of glycerol, fatty acids and alcohols, then utilized to characterize commercial glycerol and biodiesel samples. (C) 2009 Elsevier Ltd. All rights reserved.

Phosphitylation

Glycerol

Transesterification

chromatography

oil

P-31 NMR

Biodiesel

Författare

M. Nagy

Institute of Paper Science and Technology

B. J. Kerr

USDA Agricultural Research Service, Washington DC

C. J. Ziemer

USDA Agricultural Research Service, Washington DC

Art Ragauskas

Chalmers, Kemi- och bioteknik, Skogsindustriell kemiteknik

Fuel

0016-2361 (ISSN)

Vol. 88 1793-1797

Ämneskategorier

Energiteknik

DOI

10.1016/j.fuel.2009.01.020